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Aqueous Acid-Base Equilibria and Titrations (Oxford Chemistry Primers) de Robert de Levie
Descripción - Reseña del editor This book will give students a thorough grounding in pH and associated equilibria, material absolutely fundamental to the understanding of many aspects of chemistry. It is, in addition, a fresh and modern approach to a topic all too often taught in an out-moded way. This book uses new theoretical developments which have led to more generalized approaches to equilibrium problems; these approaches are often simpler than the approximations which they replace. Acid-base problems are readily addressed in terms of the proton condition, a convenient amalgam of the mass and charge constraints of the chemical system considered. The graphical approach of Bjerrum, Hägg, and Sillén is used to illustrate the orders of magnitude of the concentrations of the various species involved in chemical equilibria. Based on these concentrations, the proton condition can usually be simplified, often leading directly to the value of the pH. In the description of acid-base titrations a general master equation is developed. It provides a continuous and complete description of the entire titration curve, which can then be used for computer-based comparison with experimental data. Graphical estimates of the steepness of titration curves are also developed, from which the practicality of a given titration can be anticipated. Activity effects are described in detail, including their effect on titration curves. The discussion emphasizes the distinction between equilibrium constants and electrometric pH measurements, which are subject to activity corrections, and balance equations and spectroscopic pH measurements, which are not. Finally, an entire chapter is devoted to what the pH meter measures, and to the experimental and theoretical uncertainties involved. Biografía del autor Prof Robert de Levie, Georgetown University, Department of Chemistry, Box 571227, Washington DC 20057-1227, USA fax 202 687 6209 From July 1 1999: Chemistry Department, Bowdoin College, Brunswick ME04011, USA
Detalles del Libro
- Name: Aqueous Acid-Base Equilibria and Titrations (Oxford Chemistry Primers)
- Autor: Robert de Levie
- Categoria: Libros,Ciencias, tecnología y medicina,Biología
- Tamaño del archivo: 12 MB
- Tipos de archivo: PDF Document
- Descargada: 637 times
- Idioma: Español
- Archivos de estado: AVAILABLE
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Equilibria in aqueous solutions chemistry libretexts indicators for acidbase titrations are conjugate acidbase pairs each member of which is a different color an indicator changes from the color of the conjugate acid to the color of the conjugate base as ph increases from approximately pk in 1 to pk in 1
Aqueous acidbase equilibria and titrations paperback aqueous acidbase equilibria and titrations robert de levie publication date june 2001 isbn 9780198506171 96 pages paperback retail price to students 2500
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Aqueous acidbase equilibria and titrations book 1999 get this from a library aqueous acidbase equilibria and titrations robert de levie aqueous acidbase equilibria and titrations provides a modern introduction to ph problems acidbase problems are readily addressed in terms of the proton condition a convenient amalgam of the mass
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Aqueous acidbase equilibria and titrations robert de aqueous acidbase equilibria and titrations robert de levie authorcreator de levie robert publication oxford new york oxford university press 1999
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Aqueous acidbase equilibria and titrations in searchworks acidbase problems are readily addressed in terms of the proton condition a convenient amalgam of the mass and charge constraints of the chemical system considered the graphical approach of bjerrum hagg and sillen is used to illustrate the orders of magnitude of the concentrations of the various species involved in chemical equilibria
7 acidbase equilibria chemistry libretexts this chapter will illustrate the chemistry of acidbase reactions and equilibria and provide you with tools for quantifying the concentrations of acids and bases in solutions 71 acids and bases compounds that donate a proton a hydrogen ion to another compound is called a brønstedlowry acid